Looks as though you should follow Superfreak's advice ASAP!
Millipedes are harmless. No critter exudes HCN so far as I know! You might want to find out if their very mild venom deters predators, though.
Scorpions and spiders and centipedes normally use their venom offensively, not defensively.
Centipedes, amazingly, secrete their toxin through modified front legs called forcipules.
The comment about bombardier beetles is true. It explosively emits fluid from its butt (known technically as a wet fart) at close to boiling temperature. The liquid contains quinones and a bunch of other things that get up the would-be predator's sniffer and make it anosmic for a while.
This is all jolly good fun, but the bottom line is that you can't rely on others, who might get things wrong. Go to work!
BTW. While you're playing with Google, check out blister beetles. They're fun, too.
Oh, and grasshoppers that upchuck that green stuff. Some also secrete toxins from dorsal spines!
And don't forget caterpillars like tent pillars that emit (exude?) urticating fluid through their spines.
And..... :lol: